Potential Energy Surfaces, Transition State Theory and Reaction Mechanism - Lecture 37

Explore the fundamental concepts of reaction kinetics and mechanisms in this 48-minute lecture from Yale University's Freshman Organic Chemistry course. Delve into the statistical foundations of the law of mass action and develop a framework for understanding reaction rates using potential energy surfaces and transition state theory. Examine how collective energies and Eyring theory can be applied to predict reaction rates. Investigate free-radical chain halogenation as a practical example of predicting reaction equilibria and rates using bond dissociation energies. Conclude with a comprehensive summary of the semester's key topics in physical-organic chemistry, tying together the various concepts explored throughout the course.

- Chapter 1. The Boltzmann Factor and Entropy Against Traditional Views on Society.
- Chapter 2. The Statistical Basis of the Law of Mass Action.
- Chapter 3. Understanding Reaction Rates: The Potential Energy Surface and Collective Energies.
- Chapter 4. Free Radical Halogenations: Predicting Reaction Equilibria and Rates.
- Chapter 5. A Summary of the First Semester.