Organic Chemistry 1
Offered By: Jawaharlal Nehru University, New Delhi via Swayam
Course Description
Overview
Syllabus
We are happy to announce that this course has been very popular among learners. More than 14,350 learners had been benefited from this course. Earlier enrollments for this course: July 2019 - 3591 Jan 2020 - 3224 Aug 2020 - 2666 Jan 2021 - 2688 July 2021 - 2189 Students achievements: Shubham Pol: GPAT and NIPER- JEE qualified Suryakant Mishra: IIT-JAM qualified Sourav Adak: CSIR qualified Learner's Feedback:
"This course is very great and is helpful not only for students but also for all chemistry professors. This course is the best platform for all organic chemistry learners. The language is very easy. So that, each and every student can understand all the concepts easily. Discussion forum is also a best platform for us to ask any query about any concept.
Thank you very much sir for excellent teaching, clearing every concept in organic chemistry from basic and giving assignments to us. Keep it up sir.
Also,thanks to SWAYAM for conducting such type of course for all chemistry learners." ---- Ketaki, One of the topper from the course July-2019.
"The classes are very explanatory and very useful for the PG students and also for the faculty members. I really appreciate the efforts taken by Balaji sir. " ---Seethalakshmi S
"The course content was so relevant and insightful that every individual would definitely benefit hugely from it for their career in chemistry. The classes are very vivid, crystal clear and knowledgeable. I am very fortunate to be part of this course." ---- Ramakrishna S
"Professor Balaji did splendid job and did lots of efforts. Its been 15 days to the course have started and I am taking it right now. This course is beneficial to all as the professor took the course from basics to advance, this make learning very easy & he is very responsive which makes it very convenient." ----- Simran K
"very good nd well qualified professors.
for solving gate, net questions, dis course iz useful. thanku for efforts of all professors". ---- Anonymous
Syllabus
Week 1
Introduction to stereochemistry
Conformational analysis of open chain systems
Week 2
Conformational analysis of cyclic systems
Symmetry elements, Point group analysis
Stereochemical conventions
Week 3
Stereogenicity, Topicity
ORD and CD, Axial halo ketone rule, Octant Rule
Week 4
Stereochemical reactions
Reactions involving stereo centres
Crams Rule, Felkin-Anh model, Prelog rules
Week 5
Aromaticity, Aromatic stabilization energy, Hückel MO, Musulin-Frost diagram
Polycyclic aromatic hydrocarbon (PAH), Polyacenes, Annulene
Week 6
Aromatic Electrophilic substitutions
Aromatic Nucleophilic substitutions
Ipso-cine-tele substitution
Week 7
Reaction dynamics, Hammond postulate
Linear free energy relationship, Hammett equation
Week 8
Yukawa Tsuno equation, Swain-Lupton equation, Grunwald–Winstein equation, Taft equation
Curtin-Hammett principle, Winstein-Holness equation
Carbocation, Part 1: Generation, Structure and Geometry
Week 9
Carbocation, Part 2: Stabilisation of carbocation, Reactions
Carbocation, Rearrangement 1: No Change in carbon skeleton, Change in carbon skeleton
Carbocation, Rearrangement 2: involvement of other electron deficient terminus, Anchimeric assistance
Week 10
Carbanions: pKa and its significance
Carbanions: Hard and Soft Acid and Base principle
Carbanions: Structure, Formation, Stability, Reactivity
Week 11
Carbanion reactions: Acyl Anions, Benzoin condensation, Umpolung-inversion of reactivity
Free radical 1: Formation, Structure, Stability
Week 12
Free radical 2: Stability, Reactivity
Free radical 3: Reactions: Addition, atom abstraction, disproportionation, cyclisation
Week 13
Free radical 4: Reactions: Fenton, Kolbe, Bouveault-Blanc, Giese, Hofmann-Loffler, Birch, Barton-McCombie, Sandmeyer, Barton decarboxylation
Carbene, Nitrene: Generation, Structure, Reactivity
Week 14
Carbonyl addition reaction
Enol and enolate formation and reactions
Enamines formation and reactions
Week 15
Enol ethers formation and reactions, Mukaiyama-Aldol reaction
Sharpless epoxidation, Click reaction, Diels-Alder reaction- Scope and mechanism
Exam
Taught by
Dr. B. S. Balaji
Tags
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